<?xml version="1.0" encoding="UTF-8"?>

<!--XBRL Document Created with Wdesk from Workiva-->
<!--Copyright 2022 Workiva-->
<!--r:ed18cdbd-aeb3-4a89-8884-14c456125753,g:1da9ca8a-5745-43be-8dd0-841742fe15cb-->
<xs:schema xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:link="http://www.xbrl.org/2003/linkbase" xmlns:gevo="http://wfx.webfilings.com/20220331" xmlns:xbrli="http://www.xbrl.org/2003/instance" xmlns:dtr-types="http://www.xbrl.org/dtr/type/2020-01-21" xmlns:xbrldt="http://xbrl.org/2005/xbrldt" attributeFormDefault="unqualified" elementFormDefault="qualified" targetNamespace="http://wfx.webfilings.com/20220331">
  <xs:import namespace="http://fasb.org/srt/2021-01-31" schemaLocation="https://xbrl.fasb.org/srt/2021/elts/srt-2021-01-31.xsd"/>
  <xs:import namespace="http://fasb.org/us-gaap/2021-01-31" schemaLocation="https://xbrl.fasb.org/us-gaap/2021/elts/us-gaap-2021-01-31.xsd"/>
  <xs:import namespace="http://www.w3.org/1999/xlink" schemaLocation="http://www.xbrl.org/2003/xlink-2003-12-31.xsd"/>
  <xs:import namespace="http://www.xbrl.org/2003/instance" schemaLocation="http://www.xbrl.org/2003/xbrl-instance-2003-12-31.xsd"/>
  <xs:import namespace="http://www.xbrl.org/2003/linkbase" schemaLocation="http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd"/>
  <xs:import namespace="http://www.xbrl.org/dtr/type/2020-01-21" schemaLocation="https://www.xbrl.org/dtr/type/2020-01-21/types.xsd"/>
  <xs:import namespace="http://xbrl.org/2005/xbrldt" schemaLocation="http://www.xbrl.org/2005/xbrldt-2005.xsd"/>
  <xs:import namespace="http://xbrl.sec.gov/dei/2021" schemaLocation="https://xbrl.sec.gov/dei/2021/dei-2021.xsd"/>
  <xs:annotation>
    <xs:appinfo>
      <link:linkbaseRef xmlns:xlink="http://www.w3.org/1999/xlink" xlink:arcrole="http://www.w3.org/1999/xlink/properties/linkbase" xlink:href="gevo-20220331_lab.xml" xlink:role="http://www.xbrl.org/2003/role/labelLinkbaseRef" xlink:type="simple"/>
      <link:linkbaseRef xmlns:xlink="http://www.w3.org/1999/xlink" xlink:arcrole="http://www.w3.org/1999/xlink/properties/linkbase" xlink:href="gevo-20220331_pre.xml" xlink:role="http://www.xbrl.org/2003/role/presentationLinkbaseRef" xlink:type="simple"/>
      <link:linkbaseRef xmlns:xlink="http://www.w3.org/1999/xlink" xlink:arcrole="http://www.w3.org/1999/xlink/properties/linkbase" xlink:href="gevo-20220331_cal.xml" xlink:role="http://www.xbrl.org/2003/role/calculationLinkbaseRef" xlink:type="simple"/>
      <link:linkbaseRef xmlns:xlink="http://www.w3.org/1999/xlink" xlink:arcrole="http://www.w3.org/1999/xlink/properties/linkbase" xlink:href="gevo-20220331_def.xml" xlink:role="http://www.xbrl.org/2003/role/definitionLinkbaseRef" xlink:type="simple"/>
      <link:roleType id="Coverpage" roleURI="http://wfx.webfilings.com/role/Coverpage">
        <link:definition>0001001 - Document - Cover page</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="CONSOLIDATEDBALANCESHEETS" roleURI="http://wfx.webfilings.com/role/CONSOLIDATEDBALANCESHEETS">
        <link:definition>1001002 - Statement - CONSOLIDATED BALANCE SHEETS</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="CONSOLIDATEDBALANCESHEETSParentheticals" roleURI="http://wfx.webfilings.com/role/CONSOLIDATEDBALANCESHEETSParentheticals">
        <link:definition>1402401 - Statement - CONSOLIDATED BALANCE SHEETS (Parentheticals)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="CONSOLIDATEDSTATEMENTSOFOPERATIONS" roleURI="http://wfx.webfilings.com/role/CONSOLIDATEDSTATEMENTSOFOPERATIONS">
        <link:definition>1003003 - Statement - CONSOLIDATED STATEMENTS OF OPERATIONS</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="CONSOLIDATEDSTATEMENTSOFOPERATIONSParentheticals" roleURI="http://wfx.webfilings.com/role/CONSOLIDATEDSTATEMENTSOFOPERATIONSParentheticals">
        <link:definition>1404402 - Statement - CONSOLIDATED STATEMENTS OF OPERATIONS (Parentheticals)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="CONSOLIDATEDSTATEMENTSOFCOMPREHENSIVEINCOMELOSS" roleURI="http://wfx.webfilings.com/role/CONSOLIDATEDSTATEMENTSOFCOMPREHENSIVEINCOMELOSS">
        <link:definition>1005004 - Statement - CONSOLIDATED STATEMENTS OF COMPREHENSIVE INCOME (LOSS)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="CONSOLIDATEDSTATEMENTSOFSTOCKHOLDERSEQUITY" roleURI="http://wfx.webfilings.com/role/CONSOLIDATEDSTATEMENTSOFSTOCKHOLDERSEQUITY">
        <link:definition>1006005 - Statement - CONSOLIDATED STATEMENTS OF STOCKHOLDERS&#8217; EQUITY</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="CONSOLIDATEDSTATEMENTSOFCASHFLOWS" roleURI="http://wfx.webfilings.com/role/CONSOLIDATEDSTATEMENTSOFCASHFLOWS">
        <link:definition>1007006 - Statement - CONSOLIDATED STATEMENTS OF CASH FLOWS</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="NatureofBusinessFinancialConditionandBasisofPresentation" roleURI="http://wfx.webfilings.com/role/NatureofBusinessFinancialConditionandBasisofPresentation">
        <link:definition>2101101 - Disclosure - Nature of Business, Financial Condition and Basis of Presentation</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="NatureofBusinessFinancialConditionandBasisofPresentationPolicies" roleURI="http://wfx.webfilings.com/role/NatureofBusinessFinancialConditionandBasisofPresentationPolicies">
        <link:definition>2302301 - Disclosure - Nature of Business, Financial Condition and Basis of Presentation (Policies)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="NatureofBusinessFinancialConditionandBasisofPresentationDetails" roleURI="http://wfx.webfilings.com/role/NatureofBusinessFinancialConditionandBasisofPresentationDetails">
        <link:definition>2403403 - Disclosure - Nature of Business, Financial Condition and Basis of Presentation (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="RevenuesfromContractswithCustomersandOtherRevenues" roleURI="http://wfx.webfilings.com/role/RevenuesfromContractswithCustomersandOtherRevenues">
        <link:definition>2104102 - Disclosure - Revenues from Contracts with Customers and Other Revenues</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="RevenuesfromContractswithCustomersandOtherRevenuesNarrativeDetails" roleURI="http://wfx.webfilings.com/role/RevenuesfromContractswithCustomersandOtherRevenuesNarrativeDetails">
        <link:definition>2405404 - Disclosure - Revenues from Contracts with Customers and Other Revenues - Narrative (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="NetlossPerShare" roleURI="http://wfx.webfilings.com/role/NetlossPerShare">
        <link:definition>2106103 - Disclosure - Net loss Per Share</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="NetlossPerShareTables" roleURI="http://wfx.webfilings.com/role/NetlossPerShareTables">
        <link:definition>2307302 - Disclosure - Net loss Per Share (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="NetlossPerShareNarrativeDetails" roleURI="http://wfx.webfilings.com/role/NetlossPerShareNarrativeDetails">
        <link:definition>2408405 - Disclosure - Net loss Per Share - Narrative (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="NetlossPerShareBasicandDilutedNetLossperShareDetails" roleURI="http://wfx.webfilings.com/role/NetlossPerShareBasicandDilutedNetLossperShareDetails">
        <link:definition>2409406 - Disclosure - Net loss Per Share - Basic and Diluted Net Loss per Share (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="PrepaidandOtherCurrentAssets" roleURI="http://wfx.webfilings.com/role/PrepaidandOtherCurrentAssets">
        <link:definition>2110104 - Disclosure - Prepaid and Other Current Assets</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="PrepaidandOtherCurrentAssetsTables" roleURI="http://wfx.webfilings.com/role/PrepaidandOtherCurrentAssetsTables">
        <link:definition>2311303 - Disclosure - Prepaid and Other Current Assets (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="PrepaidandOtherCurrentAssetsDetails" roleURI="http://wfx.webfilings.com/role/PrepaidandOtherCurrentAssetsDetails">
        <link:definition>2412407 - Disclosure - Prepaid and Other Current Assets (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="MarketableSecurities" roleURI="http://wfx.webfilings.com/role/MarketableSecurities">
        <link:definition>2113105 - Disclosure - Marketable Securities</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="MarketableSecuritiesTables" roleURI="http://wfx.webfilings.com/role/MarketableSecuritiesTables">
        <link:definition>2314304 - Disclosure - Marketable Securities (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="MarketableSecuritiesInvestmentsInMarketableSecuritiesDetails" roleURI="http://wfx.webfilings.com/role/MarketableSecuritiesInvestmentsInMarketableSecuritiesDetails">
        <link:definition>2415408 - Disclosure - Marketable Securities - Investments In Marketable Securities (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="MarketableSecuritiesNarrativeDetails" roleURI="http://wfx.webfilings.com/role/MarketableSecuritiesNarrativeDetails">
        <link:definition>2416409 - Disclosure - Marketable Securities - Narrative (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="LeasesRightofUseAssetsandRelatedLiabilities" roleURI="http://wfx.webfilings.com/role/LeasesRightofUseAssetsandRelatedLiabilities">
        <link:definition>2117106 - Disclosure - Leases, Right-of-Use Assets and Related Liabilities</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="LeasesRightofUseAssetsandRelatedLiabilitiesTables" roleURI="http://wfx.webfilings.com/role/LeasesRightofUseAssetsandRelatedLiabilitiesTables">
        <link:definition>2318305 - Disclosure - Leases, Right-of-Use Assets and Related Liabilities (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="LeasesRightofUseAssetsandRelatedLiabilitiesNarrativeDetails" roleURI="http://wfx.webfilings.com/role/LeasesRightofUseAssetsandRelatedLiabilitiesNarrativeDetails">
        <link:definition>2419410 - Disclosure - Leases, Right-of-Use Assets and Related Liabilities - Narrative (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="LeasesRightofUseAssetsandRelatedLiabilitiesLeaseCostDetails" roleURI="http://wfx.webfilings.com/role/LeasesRightofUseAssetsandRelatedLiabilitiesLeaseCostDetails">
        <link:definition>2420411 - Disclosure - Leases, Right-of-Use Assets and Related Liabilities - Lease Cost (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="LeasesRightofUseAssetsandRelatedLiabilitiesOtherInformationDetails" roleURI="http://wfx.webfilings.com/role/LeasesRightofUseAssetsandRelatedLiabilitiesOtherInformationDetails">
        <link:definition>2421412 - Disclosure - Leases, Right-of-Use Assets and Related Liabilities - Other Information (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="LeasesRightofUseAssetsandRelatedLiabilitiesFutureMinimumPaymentsUnderNonCancelableDetails" roleURI="http://wfx.webfilings.com/role/LeasesRightofUseAssetsandRelatedLiabilitiesFutureMinimumPaymentsUnderNonCancelableDetails">
        <link:definition>2422413 - Disclosure - Leases, Right-of-Use Assets and Related Liabilities - Future Minimum Payments Under Non-Cancelable (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="LeasesRightofUseAssetsandRelatedLiabilitiesFutureMinimumPaymentsUnderNonCancelableDetails_1" roleURI="http://wfx.webfilings.com/role/LeasesRightofUseAssetsandRelatedLiabilitiesFutureMinimumPaymentsUnderNonCancelableDetails_1">
        <link:definition>2422413 - Disclosure - Leases, Right-of-Use Assets and Related Liabilities - Future Minimum Payments Under Non-Cancelable (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="Inventories" roleURI="http://wfx.webfilings.com/role/Inventories">
        <link:definition>2123107 - Disclosure - Inventories</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="InventoriesTables" roleURI="http://wfx.webfilings.com/role/InventoriesTables">
        <link:definition>2324306 - Disclosure - Inventories (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="InventoriesComponentsofInventoryBalancesDetails" roleURI="http://wfx.webfilings.com/role/InventoriesComponentsofInventoryBalancesDetails">
        <link:definition>2425414 - Disclosure - Inventories - Components of Inventory Balances (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="InventoriesNarrativeDetails" roleURI="http://wfx.webfilings.com/role/InventoriesNarrativeDetails">
        <link:definition>2426415 - Disclosure - Inventories - Narrative (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="PropertyPlantandEquipment" roleURI="http://wfx.webfilings.com/role/PropertyPlantandEquipment">
        <link:definition>2127108 - Disclosure - Property, Plant, and Equipment</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="PropertyPlantandEquipmentTables" roleURI="http://wfx.webfilings.com/role/PropertyPlantandEquipmentTables">
        <link:definition>2328307 - Disclosure - Property, Plant, and Equipment (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="PropertyPlantandEquipmentPropertyPlantandEquipmentbyClassificationDetails" roleURI="http://wfx.webfilings.com/role/PropertyPlantandEquipmentPropertyPlantandEquipmentbyClassificationDetails">
        <link:definition>2429416 - Disclosure - Property, Plant, and Equipment - Property, Plant and Equipment by Classification (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="PropertyPlantandEquipmentDepreciationandAmortizationExpenseDetails" roleURI="http://wfx.webfilings.com/role/PropertyPlantandEquipmentDepreciationandAmortizationExpenseDetails">
        <link:definition>2430417 - Disclosure - Property, Plant, and Equipment - Depreciation and Amortization Expense (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="PropertyPlantandEquipmentNarrativeDetails" roleURI="http://wfx.webfilings.com/role/PropertyPlantandEquipmentNarrativeDetails">
        <link:definition>2431418 - Disclosure - Property, Plant, and Equipment - Narrative (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="IntangibleAssets" roleURI="http://wfx.webfilings.com/role/IntangibleAssets">
        <link:definition>2132109 - Disclosure - Intangible Assets</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="IntangibleAssetsTables" roleURI="http://wfx.webfilings.com/role/IntangibleAssetsTables">
        <link:definition>2333308 - Disclosure - Intangible Assets (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="IntangibleAssetsIdentifiableIntangibleAssetsDetails" roleURI="http://wfx.webfilings.com/role/IntangibleAssetsIdentifiableIntangibleAssetsDetails">
        <link:definition>2434419 - Disclosure - Intangible Assets - Identifiable Intangible Assets (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="IntangibleAssetsEstimatedAmortizationofIdentifiableIntangibleAssetsDetails" roleURI="http://wfx.webfilings.com/role/IntangibleAssetsEstimatedAmortizationofIdentifiableIntangibleAssetsDetails">
        <link:definition>2435420 - Disclosure - Intangible Assets - Estimated Amortization of Identifiable Intangible Assets (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="Warrants" roleURI="http://wfx.webfilings.com/role/Warrants">
        <link:definition>2136110 - Disclosure - Warrants</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="WarrantsTables" roleURI="http://wfx.webfilings.com/role/WarrantsTables">
        <link:definition>2337309 - Disclosure - Warrants (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="WarrantsNarrativeDetails" roleURI="http://wfx.webfilings.com/role/WarrantsNarrativeDetails">
        <link:definition>2438421 - Disclosure - Warrants - Narrative (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="WarrantsSharesIssuedUponExerciseofWarrantsDetails" roleURI="http://wfx.webfilings.com/role/WarrantsSharesIssuedUponExerciseofWarrantsDetails">
        <link:definition>2439422 - Disclosure - Warrants - Shares Issued Upon Exercise of Warrants (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="WarrantsExerciseofWarrantsDetails" roleURI="http://wfx.webfilings.com/role/WarrantsExerciseofWarrantsDetails">
        <link:definition>2440423 - Disclosure - Warrants - Exercise of Warrants (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="AccountsPayableandAccruedLiabilities" roleURI="http://wfx.webfilings.com/role/AccountsPayableandAccruedLiabilities">
        <link:definition>2141111 - Disclosure - Accounts Payable and Accrued Liabilities</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="AccountsPayableandAccruedLiabilitiesTables" roleURI="http://wfx.webfilings.com/role/AccountsPayableandAccruedLiabilitiesTables">
        <link:definition>2342310 - Disclosure - Accounts Payable and Accrued Liabilities (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="AccountsPayableandAccruedLiabilitiesDetails" roleURI="http://wfx.webfilings.com/role/AccountsPayableandAccruedLiabilitiesDetails">
        <link:definition>2443424 - Disclosure - Accounts Payable and Accrued Liabilities (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="Debt" roleURI="http://wfx.webfilings.com/role/Debt">
        <link:definition>2144112 - Disclosure - Debt</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="DebtTables" roleURI="http://wfx.webfilings.com/role/DebtTables">
        <link:definition>2345311 - Disclosure - Debt (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="DebtNarrativeDetails" roleURI="http://wfx.webfilings.com/role/DebtNarrativeDetails">
        <link:definition>2446425 - Disclosure - Debt - Narrative (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="DebtRestrictedCashHeldbyBondTrusteeDetails" roleURI="http://wfx.webfilings.com/role/DebtRestrictedCashHeldbyBondTrusteeDetails">
        <link:definition>2447426 - Disclosure - Debt - Restricted Cash Held by Bond Trustee (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="Debt2021BondsandLoansPayableOtherDetails" roleURI="http://wfx.webfilings.com/role/Debt2021BondsandLoansPayableOtherDetails">
        <link:definition>2448427 - Disclosure - Debt - 2021 Bonds and Loans Payable - Other (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="DebtFuturePrincipalPaymentsforLongtermDebtDetails" roleURI="http://wfx.webfilings.com/role/DebtFuturePrincipalPaymentsforLongtermDebtDetails">
        <link:definition>2449428 - Disclosure - Debt - Future Principal Payments for Long-term Debt (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="DepositsandOtherAssets" roleURI="http://wfx.webfilings.com/role/DepositsandOtherAssets">
        <link:definition>2050007 - Disclosure - Deposits and Other Assets</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="DepositsandOtherAssetsTables" roleURI="http://wfx.webfilings.com/role/DepositsandOtherAssetsTables">
        <link:definition>2351312 - Disclosure - Deposits and Other Assets (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="DepositsandOtherAssetsDetails" roleURI="http://wfx.webfilings.com/role/DepositsandOtherAssetsDetails">
        <link:definition>2452429 - Disclosure - Deposits and Other Assets (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="StockBasedCompensation" roleURI="http://wfx.webfilings.com/role/StockBasedCompensation">
        <link:definition>2153113 - Disclosure - Stock-Based Compensation</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="StockBasedCompensationTables" roleURI="http://wfx.webfilings.com/role/StockBasedCompensationTables">
        <link:definition>2354313 - Disclosure - Stock-Based Compensation (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="StockBasedCompensationNarrativeDetails" roleURI="http://wfx.webfilings.com/role/StockBasedCompensationNarrativeDetails">
        <link:definition>2455430 - Disclosure - Stock-Based Compensation - Narrative (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="StockBasedCompensationRestrictedCommonStockandNonqualifiedStockOptionActivityDetails" roleURI="http://wfx.webfilings.com/role/StockBasedCompensationRestrictedCommonStockandNonqualifiedStockOptionActivityDetails">
        <link:definition>2456431 - Disclosure - Stock-Based Compensation - Restricted Common Stock and Non-qualified Stock Option Activity (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="StockbasedCompensationStockbasedCompensationExpenseDetails" roleURI="http://wfx.webfilings.com/role/StockbasedCompensationStockbasedCompensationExpenseDetails">
        <link:definition>2457432 - Disclosure - Stock-based Compensation - Stock-based Compensation Expense (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="StockbasedCompensationStockOptionAwardActivityDetails" roleURI="http://wfx.webfilings.com/role/StockbasedCompensationStockOptionAwardActivityDetails">
        <link:definition>2458433 - Disclosure - Stock-based Compensation - Stock Option Award Activity (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="StockbasedCompensationNonvestedRestrictedStockDetails" roleURI="http://wfx.webfilings.com/role/StockbasedCompensationNonvestedRestrictedStockDetails">
        <link:definition>2459434 - Disclosure - Stock-based Compensation - Non-vested Restricted Stock (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="IncomeTaxes" roleURI="http://wfx.webfilings.com/role/IncomeTaxes">
        <link:definition>2160114 - Disclosure - Income Taxes</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="CommitmentsandContingencies" roleURI="http://wfx.webfilings.com/role/CommitmentsandContingencies">
        <link:definition>2161115 - Disclosure - Commitments and Contingencies</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="CommitmentsandContingenciesDetails" roleURI="http://wfx.webfilings.com/role/CommitmentsandContingenciesDetails">
        <link:definition>2462435 - Disclosure - Commitments and Contingencies (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="FairValueMeasurements" roleURI="http://wfx.webfilings.com/role/FairValueMeasurements">
        <link:definition>2163116 - Disclosure - Fair Value Measurements</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="FairValueMeasurementsTables" roleURI="http://wfx.webfilings.com/role/FairValueMeasurementsTables">
        <link:definition>2364314 - Disclosure - Fair Value Measurements (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="FairValueMeasurementsFairValueMeasurementsRecurringandNonrecurringDetails" roleURI="http://wfx.webfilings.com/role/FairValueMeasurementsFairValueMeasurementsRecurringandNonrecurringDetails">
        <link:definition>2465436 - Disclosure - Fair Value Measurements - Fair Value Measurements, Recurring and Nonrecurring (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="FairValueMeasurementsCarryingValuesandEstimatedFairValuesDetails" roleURI="http://wfx.webfilings.com/role/FairValueMeasurementsCarryingValuesandEstimatedFairValuesDetails">
        <link:definition>2466437 - Disclosure - Fair Value Measurements - Carrying Values and Estimated Fair Values (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="Segments" roleURI="http://wfx.webfilings.com/role/Segments">
        <link:definition>2167117 - Disclosure - Segments</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="SegmentsTables" roleURI="http://wfx.webfilings.com/role/SegmentsTables">
        <link:definition>2368315 - Disclosure - Segments (Tables)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="SegmentsNarrativeDetails" roleURI="http://wfx.webfilings.com/role/SegmentsNarrativeDetails">
        <link:definition>2469438 - Disclosure - Segments- Narrative (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="SegmentsSegmentReportingInformationDetails" roleURI="http://wfx.webfilings.com/role/SegmentsSegmentReportingInformationDetails">
        <link:definition>2470439 - Disclosure - Segments - Segment Reporting Information (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="SubsequentEvents" roleURI="http://wfx.webfilings.com/role/SubsequentEvents">
        <link:definition>2171118 - Disclosure - Subsequent Events</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
      <link:roleType id="SubsequentEventsDetails" roleURI="http://wfx.webfilings.com/role/SubsequentEventsDetails">
        <link:definition>2472440 - Disclosure - Subsequent Events (Details)</link:definition>
        <link:usedOn>link:presentationLink</link:usedOn>
        <link:usedOn>link:calculationLink</link:usedOn>
        <link:usedOn>link:definitionLink</link:usedOn>
      </link:roleType>
    </xs:appinfo>
  </xs:annotation>
  <xs:element id="gevo_NonqualifiedStockOptionsMember" abstract="true" name="NonqualifiedStockOptionsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_PalladiumMember" abstract="true" name="PalladiumMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_GevoMember" abstract="true" name="GevoMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_EquityClassifiedAwardsMember" abstract="true" name="EquityClassifiedAwardsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_PaymentsToAcquireIntangibleAssetsPlantPropertyAndEquipment" abstract="false" name="PaymentsToAcquireIntangibleAssetsPlantPropertyAndEquipment" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_HydrocarbonMember" abstract="true" name="HydrocarbonMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_CashDepositedInBank" abstract="false" name="CashDepositedInBank" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_IsobutanolMember" abstract="true" name="IsobutanolMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_CashPaidForInterestCapitalizedToConstructionInProgress" abstract="false" name="CashPaidForInterestCapitalizedToConstructionInProgress" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_ClassOfWarrantOrRightUnexercisedAndExpired" abstract="false" name="ClassOfWarrantOrRightUnexercisedAndExpired" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="gevo_AccruedProjectCostsCurrent" abstract="false" name="AccruedProjectCostsCurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_NoncashInterestCapitalizedToConstructionInProgress" abstract="false" name="NoncashInterestCapitalizedToConstructionInProgress" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_StockIssuedDuringPeriodValuesWarrantsExercised" abstract="false" name="StockIssuedDuringPeriodValuesWarrantsExercised" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_PreliminaryStageProjectsMember" abstract="true" name="PreliminaryStageProjectsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_LabEquipmentFurnitureAndFixturesAndVehiclesMember" abstract="true" name="LabEquipmentFurnitureAndFixturesAndVehiclesMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_NonCashLeaseExpense" abstract="false" name="NonCashLeaseExpense" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_RestrictedCashAndCashEquivalentsDisbursementOfFunds" abstract="false" name="RestrictedCashAndCashEquivalentsDisbursementOfFunds" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_SeriesKWarrantsMember" abstract="true" name="SeriesKWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_LuverneMinnesotaMember" abstract="true" name="LuverneMinnesotaMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_ExclusivityFeesCurrent" abstract="false" name="ExclusivityFeesCurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_FinanceLeaseLiabilityToBePaidAfterYearFour" abstract="false" name="FinanceLeaseLiabilityToBePaidAfterYearFour" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_ContractWithCustomerRevenueAndTradeReceivablesRecordedAsPercentageOfTransactionPrice" abstract="false" name="ContractWithCustomerRevenueAndTradeReceivablesRecordedAsPercentageOfTransactionPrice" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:percentItemType"/>
  <xs:element id="gevo_PaymentOfFinanceLeaseLiabilities" abstract="false" name="PaymentOfFinanceLeaseLiabilities" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_AccountsPayableAndAccruedLiabilitiesLineItems" abstract="true" name="AccountsPayableAndAccruedLiabilitiesLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_EquipmentLoansMember" abstract="true" name="EquipmentLoansMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_CornMember" abstract="true" name="CornMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_StockIncentivePlan2010Member" abstract="true" name="StockIncentivePlan2010Member" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RestrictedCashAndCashEquivalentsInterestIncome" abstract="false" name="RestrictedCashAndCashEquivalentsInterestIncome" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_RestrictedCashAndCashEquivalentsRestrictedCashForCollateral" abstract="false" name="RestrictedCashAndCashEquivalentsRestrictedCashForCollateral" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_CommonSharesIssuedUponExerciseOfWarrants" abstract="false" name="CommonSharesIssuedUponExerciseOfWarrants" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="gevo_EmployeeStockPurchasePlanMember" abstract="true" name="EmployeeStockPurchasePlanMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsNoncurrentExclusivityFees" abstract="false" name="DepositsAndOtherAssetsNoncurrentExclusivityFees" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_RenewableNaturalGasSuppliesNumberOfDairies" abstract="false" name="RenewableNaturalGasSuppliesNumberOfDairies" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_DemonstrationPlantMember" abstract="true" name="DemonstrationPlantMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DigesterProductionCapacity" abstract="false" name="DigesterProductionCapacity" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:energyItemType"/>
  <xs:element id="gevo_AgriEnergyMember" abstract="true" name="AgriEnergyMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_AgriEnergySegmentMember" abstract="true" name="AgriEnergySegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RenewableNaturalGasSuppliesNumberOfMilkingCows" abstract="false" name="RenewableNaturalGasSuppliesNumberOfMilkingCows" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_DefensiveAssetsMember" abstract="true" name="DefensiveAssetsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_StockIssuedDuringPeriodSharesWarrantsExercised" abstract="false" name="StockIssuedDuringPeriodSharesWarrantsExercised" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="gevo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisedInPeriodWeightedAverageGrantDateFairValue" abstract="false" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisedInPeriodWeightedAverageGrantDateFairValue" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:perShareItemType"/>
  <xs:element id="gevo_ProceedsFromIssuanceOfBondsUsed" abstract="false" name="ProceedsFromIssuanceOfBondsUsed" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsTextBlock" abstract="false" name="DepositsAndOtherAssetsTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
  <xs:element id="gevo_NatureOfBusinessFinancialConditionAndBasisOfPresentationLineItems" abstract="true" name="NatureOfBusinessFinancialConditionAndBasisOfPresentationLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_LiabilityClassifiedAwardsMember" abstract="true" name="LiabilityClassifiedAwardsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DebtSecuritiesAvailableForSaleNoncurrentAccumulatedGrossUnrealizedLossBeforeTax" abstract="false" name="DebtSecuritiesAvailableForSaleNoncurrentAccumulatedGrossUnrealizedLossBeforeTax" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_GevoSegmentMember" abstract="true" name="GevoSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_IndemnificationLiabilities" abstract="false" name="IndemnificationLiabilities" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_PaymentsForNetSettlementOfCommonStockUnderStockPlans" abstract="false" name="PaymentsForNetSettlementOfCommonStockUnderStockPlans" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_LiabilityClassifiedRestrictedStockAwardsFairValue" abstract="false" name="LiabilityClassifiedRestrictedStockAwardsFairValue" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_PrepaidFeesCurrent" abstract="false" name="PrepaidFeesCurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_FinanceLeasePercentageOfFuelSuppliesToMoveCapitalizedAmountToInventory" abstract="false" name="FinanceLeasePercentageOfFuelSuppliesToMoveCapitalizedAmountToInventory" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:percentItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsTableTextBlock" abstract="false" name="DepositsAndOtherAssetsTableTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
  <xs:element id="gevo_RestrictedStockLiabilityClassifiedAwardsMember" abstract="true" name="RestrictedStockLiabilityClassifiedAwardsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsNoncurrent" abstract="false" name="DepositsAndOtherAssetsNoncurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_LesseeOperatingLeaseLiabilityToBePaidAfterYearFour" abstract="false" name="LesseeOperatingLeaseLiabilityToBePaidAfterYearFour" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_NetZeroSegmentMember" abstract="true" name="NetZeroSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_A2021BondsMember" abstract="true" name="A2021BondsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_FiniteLivedIntangibleAssetExpectedAmortizationAfterYearFour" abstract="false" name="FiniteLivedIntangibleAssetExpectedAmortizationAfterYearFour" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_LeaseholdImprovementsPilotPlantLandAndSupportEquipmentMember" abstract="true" name="LeaseholdImprovementsPilotPlantLandAndSupportEquipmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_ScheduleOfEquityIncentivePlansLineItems" abstract="true" name="ScheduleOfEquityIncentivePlansLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_EthanolSalesAndRelatedProductsMember" abstract="true" name="EthanolSalesAndRelatedProductsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_GainLossFromChangeInFairValueOfDerivativeWarrantLiability" abstract="false" name="GainLossFromChangeInFairValueOfDerivativeWarrantLiability" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_SiteImprovementMember" abstract="true" name="SiteImprovementMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_NatureOfBusinessFinancialConditionAndBasisOfPresentationTable" abstract="true" name="NatureOfBusinessFinancialConditionAndBasisOfPresentationTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType"/>
  <xs:element id="gevo_SBALoansMember" abstract="true" name="SBALoansMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsNoncurrentInvestment" abstract="false" name="DepositsAndOtherAssetsNoncurrentInvestment" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_ProceedsFromIssuanceOfBondsUnused" abstract="false" name="ProceedsFromIssuanceOfBondsUnused" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_RetrofitAssetsMember" abstract="true" name="RetrofitAssetsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RestrictedCashAndCashEquivalentsBondProceeds" abstract="false" name="RestrictedCashAndCashEquivalentsBondProceeds" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_RenewableNaturalGasSegmentMember" abstract="true" name="RenewableNaturalGasSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_ScheduleOfDepreciationAndAmortizationExpenseTableTextBlock" abstract="false" name="ScheduleOfDepreciationAndAmortizationExpenseTableTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
  <xs:element id="gevo_Series2020AWarrantsMember" abstract="true" name="Series2020AWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_SAFIsooctaneAndIsoocteneMember" abstract="true" name="SAFIsooctaneAndIsoocteneMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DebtSecuritiesAvailableForSaleCurrentAccumulatedGrossUnrealizedLossBeforeTax" abstract="false" name="DebtSecuritiesAvailableForSaleCurrentAccumulatedGrossUnrealizedLossBeforeTax" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_CostOfProductionMember" abstract="true" name="CostOfProductionMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_VariableRevenues" abstract="false" name="VariableRevenues" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_NWLowaRNGSegmentMember" abstract="true" name="NWLowaRNGSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_NumberOfOperatingPlants" abstract="false" name="NumberOfOperatingPlants" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_NumberOfDigesterSites" abstract="false" name="NumberOfDigesterSites" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_NutrientsMember" abstract="true" name="NutrientsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_FinanceLeasePercentageOfFuelSupplies" abstract="false" name="FinanceLeasePercentageOfFuelSupplies" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:percentItemType"/>
  <xs:element id="gevo_ComputerOfficeEquipmentAndSoftwareMember" abstract="true" name="ComputerOfficeEquipmentAndSoftwareMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_LesseeFinanceLeaseNumberOfContract" abstract="false" name="LesseeFinanceLeaseNumberOfContract" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_RestrictedCashAndCashEquivalentsInterestPaidOnBonds" abstract="false" name="RestrictedCashAndCashEquivalentsInterestPaidOnBonds" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_RestrictedCashAndCashEquivalentsHeldByBondTrustee" abstract="false" name="RestrictedCashAndCashEquivalentsHeldByBondTrustee" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_CashFlowLesseeAbstract" abstract="true" name="CashFlowLesseeAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_ScheduleOfEquityIncentivePlansTable" abstract="true" name="ScheduleOfEquityIncentivePlansTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType"/>
  <xs:element id="gevo_AccountsPayableAndAccruedLiabilitiesTable" abstract="true" name="AccountsPayableAndAccruedLiabilitiesTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType"/>
  <xs:element id="gevo_EnzymesAndOtherInputsMember" abstract="true" name="EnzymesAndOtherInputsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_EthanolMember" abstract="true" name="EthanolMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_PrepaidEngineering" abstract="false" name="PrepaidEngineering" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_PreliminaryStageProjectCosts" abstract="false" name="PreliminaryStageProjectCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
</xs:schema>
