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  <xsd:import namespace="http://xbrl.sec.gov/cyd-af-sub/2024" schemaLocation="https://xbrl.sec.gov/cyd/2024/cyd-af-sub-2024.xsd" />
  <xsd:element id="gevo_ProjectProductionCapacityVolumePerYear" abstract="false" name="ProjectProductionCapacityVolumePerYear" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:volumeItemType" />
  <xsd:element id="gevo_PrepaidFeedstockNoncurrent" abstract="false" name="PrepaidFeedstockNoncurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_LuverneMinnesotaMember" abstract="true" name="LuverneMinnesotaMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_NatureOfBusinessFinancialConditionAndBasisOfPresentationTable" abstract="true" name="NatureOfBusinessFinancialConditionAndBasisOfPresentationTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType" />
  <xsd:element id="gevo_CommitmentDomain" abstract="true" name="CommitmentDomain" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisedInPeriodWeightedAverageGrantDateFairValue" abstract="false" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisedInPeriodWeightedAverageGrantDateFairValue" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:perShareItemType" />
  <xsd:element id="gevo_EquipmentLoansMember" abstract="true" name="EquipmentLoansMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_ProjectDevelopmentCostsPolicyPolicyTextBlock" abstract="false" name="ProjectDevelopmentCostsPolicyPolicyTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType" />
  <xsd:element id="gevo_ScheduleOfEquityIncentivePlansLineItems" abstract="true" name="ScheduleOfEquityIncentivePlansLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsLineItems" abstract="true" name="DepositsAndOtherAssetsLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType" />
  <xsd:element id="gevo_SaleOfStockRemainingCapacityAvailableAmount" abstract="false" name="SaleOfStockRemainingCapacityAvailableAmount" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_EnvironmentalAttributeInventoryPolicyPolicyTextBlock" abstract="false" name="EnvironmentalAttributeInventoryPolicyPolicyTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType" />
  <xsd:element id="gevo_RestrictedCashInterestIncome" abstract="false" name="RestrictedCashInterestIncome" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentEquityInterest" abstract="false" name="DepositsAndOtherAssetsNoncurrentEquityInterest" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_CollaborativeArrangementReimbursableCosts" abstract="false" name="CollaborativeArrangementReimbursableCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_ProjectProductionCapacityPoundPerYear" abstract="false" name="ProjectProductionCapacityPoundPerYear" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:massItemType" />
  <xsd:element id="gevo_FuelSupplyPaymentsMember" abstract="true" name="FuelSupplyPaymentsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_PlantFacilitiesAndInfrastructureMember" abstract="true" name="PlantFacilitiesAndInfrastructureMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_SBALoansMember" abstract="true" name="SBALoansMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_StockIncentivePlan2010Member" abstract="true" name="StockIncentivePlan2010Member" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_EquityClassifiedAwardsMember" abstract="true" name="EquityClassifiedAwardsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_PowerLetterOfCreditMember" abstract="true" name="PowerLetterOfCreditMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_AtTheMarketOfferingMember" abstract="true" name="AtTheMarketOfferingMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_StockIssuedDuringPeriodSharesWarrantsExercised" abstract="false" name="StockIssuedDuringPeriodSharesWarrantsExercised" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:sharesItemType" />
  <xsd:element id="gevo_CashFlowLesseeAbstract" abstract="true" name="CashFlowLesseeAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType" />
  <xsd:element id="gevo_Series2020AWarrantsMember" abstract="true" name="Series2020AWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsTextBlock" abstract="false" name="DepositsAndOtherAssetsTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType" />
  <xsd:element id="gevo_Series2022AWarrantsMember" abstract="true" name="Series2022AWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_AgriEnergySegmentMember" abstract="true" name="AgriEnergySegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrent" abstract="false" name="DepositsAndOtherAssetsNoncurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_LakePrestonSouthDakotaMember" abstract="true" name="LakePrestonSouthDakotaMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsTableTextBlock" abstract="false" name="DepositsAndOtherAssetsTableTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentDepositsReceivableFullyReimbursedUponCompletion" abstract="false" name="DepositsAndOtherAssetsNoncurrentDepositsReceivableFullyReimbursedUponCompletion" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentOtherAssetsNet" abstract="false" name="DepositsAndOtherAssetsNoncurrentOtherAssetsNet" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DeferredTaxAssetsLeaseLiabilities" abstract="false" name="DeferredTaxAssetsLeaseLiabilities" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentDepositsReceivableReimbursedOrUsedAsInvestment" abstract="false" name="DepositsAndOtherAssetsNoncurrentDepositsReceivableReimbursedOrUsedAsInvestment" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_ScheduleOfEquityIncentivePlansTable" abstract="true" name="ScheduleOfEquityIncentivePlansTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType" />
  <xsd:element id="gevo_BondLetterOfCreditMember" abstract="true" name="BondLetterOfCreditMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_ElectricityAboveUseEstimatedMember" abstract="true" name="ElectricityAboveUseEstimatedMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_EnvironmentalAttributesMember" abstract="true" name="EnvironmentalAttributesMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_RenewableNaturalGasCommodityMember" abstract="true" name="RenewableNaturalGasCommodityMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_HydrocarbonMember" abstract="true" name="HydrocarbonMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_DevelopmentAgreementWithZero6Member" abstract="true" name="DevelopmentAgreementWithZero6Member" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_TwentyTwentyOneBondsMember" abstract="true" name="TwentyTwentyOneBondsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_LesseeFinanceLeaseNumberOfContract" abstract="false" name="LesseeFinanceLeaseNumberOfContract" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType" />
  <xsd:element id="gevo_NumberOfCommitmentsWithCollateral" abstract="false" name="NumberOfCommitmentsWithCollateral" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:integerItemType" />
  <xsd:element id="gevo_HighValueProteinProductsMember" abstract="true" name="HighValueProteinProductsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_CollaborativeArrangementAdvancedDevelopmentFeePaymentsCommitted" abstract="false" name="CollaborativeArrangementAdvancedDevelopmentFeePaymentsCommitted" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_RenewableNaturalGasSuppliesNumberOfDairies" abstract="false" name="RenewableNaturalGasSuppliesNumberOfDairies" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType" />
  <xsd:element id="gevo_DefensiveAssetsMember" abstract="true" name="DefensiveAssetsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_CommitmentCollateralPercentageOfRenewableEnergyCredits" abstract="false" name="CommitmentCollateralPercentageOfRenewableEnergyCredits" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:percentItemType" />
  <xsd:element id="gevo_Zero6Member" abstract="true" name="Zero6Member" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_BorrowingCostsPolicyPolicyTextBlock" abstract="false" name="BorrowingCostsPolicyPolicyTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType" />
  <xsd:element id="gevo_DeferredTaxAssetsOperatingLeaseAssets" abstract="false" name="DeferredTaxAssetsOperatingLeaseAssets" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DefinedContributionPlanEmployerMatchingContributionAdditionalPercentOfMatch" abstract="false" name="DefinedContributionPlanEmployerMatchingContributionAdditionalPercentOfMatch" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:percentItemType" />
  <xsd:element id="gevo_CommitmentAxis" abstract="true" name="CommitmentAxis" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:dimensionItem" type="xbrli:stringItemType" />
  <xsd:element id="gevo_RenewableEnergyCreditsMember" abstract="true" name="RenewableEnergyCreditsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_DeferredTaxAssetsCapitalizedResearchCost" abstract="false" name="DeferredTaxAssetsCapitalizedResearchCost" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DefinedContributionPlanEmployerMatchingContributionPercentOfEmployeesElectiveContributions" abstract="false" name="DefinedContributionPlanEmployerMatchingContributionPercentOfEmployeesElectiveContributions" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:percentItemType" />
  <xsd:element id="gevo_IdleFacilityCosts" abstract="false" name="IdleFacilityCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_CommonSharesIssuedUponExerciseOfWarrants" abstract="false" name="CommonSharesIssuedUponExerciseOfWarrants" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:sharesItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentExclusivityFees" abstract="false" name="DepositsAndOtherAssetsNoncurrentExclusivityFees" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsTable" abstract="true" name="DepositsAndOtherAssetsTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType" />
  <xsd:element id="gevo_CollaborativeArrangementDevelopmentChargesCommittedToPay" abstract="false" name="CollaborativeArrangementDevelopmentChargesCommittedToPay" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_CornOilMember" abstract="true" name="CornOilMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_NatureOfBusinessFinancialConditionAndBasisOfPresentationLineItems" abstract="true" name="NatureOfBusinessFinancialConditionAndBasisOfPresentationLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType" />
  <xsd:element id="gevo_NumberOfDigesterSites" abstract="false" name="NumberOfDigesterSites" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType" />
  <xsd:element id="gevo_GevoSegmentMember" abstract="true" name="GevoSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_DefinedContributionPlanEmployerMatchingContributionPercentOfEmployeesElectiveContributionsAdditional" abstract="false" name="DefinedContributionPlanEmployerMatchingContributionPercentOfEmployeesElectiveContributionsAdditional" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:percentItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentDepositsReceivable" abstract="false" name="DepositsAndOtherAssetsNoncurrentDepositsReceivable" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_WarrantsPolicyPolicyTextBlock" abstract="false" name="WarrantsPolicyPolicyTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType" />
  <xsd:element id="gevo_IndemnificationLiabilities" abstract="false" name="IndemnificationLiabilities" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_StockIssuedDuringPeriodValuesWarrantsExercised" abstract="false" name="StockIssuedDuringPeriodValuesWarrantsExercised" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_CollaborativeArrangementDevelopmentChargesCommittedUponCompletion" abstract="false" name="CollaborativeArrangementDevelopmentChargesCommittedUponCompletion" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_RenewableNaturalGasSegmentMember" abstract="true" name="RenewableNaturalGasSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_ProjectDevelopmentCosts" abstract="false" name="ProjectDevelopmentCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_FinanceLeasesFinanceCashFlowsNet" abstract="false" name="FinanceLeasesFinanceCashFlowsNet" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_SustainableAviationFuelMember" abstract="true" name="SustainableAviationFuelMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_Zero6CommitmentMember" abstract="true" name="Zero6CommitmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_DebtInstrumentPercentageOfPrincipalPaymentOnMaturityDate" abstract="false" name="DebtInstrumentPercentageOfPrincipalPaymentOnMaturityDate" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:percentItemType" />
  <xsd:element id="gevo_PrepaidFeedstockCurrent" abstract="false" name="PrepaidFeedstockCurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element name="WarrantsExercised" id="gevo_WarrantsExercised" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="NumberOfLongTermFuelSupplyContracts" id="gevo_NumberOfLongTermFuelSupplyContracts" type="xbrli:integerItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="LicensingAndDevelopmentRevenueMember" id="gevo_LicensingAndDevelopmentRevenueMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="EffectiveIncomeTaxRateReconciliationOfficersCompensationLimit" id="gevo_EffectiveIncomeTaxRateReconciliationOfficersCompensationLimit" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="DefinedContributionPlanEmployerAccruedMatchingContributions" id="gevo_DefinedContributionPlanEmployerAccruedMatchingContributions" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="AggregateOfferingPrice" id="gevo_AggregateOfferingPrice" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="PatrickGruberMember" id="gevo_PatrickGruberMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PaulBloomMember" id="gevo_PaulBloomMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="TradeAccountsReceivableNetMember" id="gevo_TradeAccountsReceivableNetMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="CustomerOneMember" id="gevo_CustomerOneMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="CostsIncurredProjectDevelopmentCosts" id="gevo_CostsIncurredProjectDevelopmentCosts" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="NoticeOfGrantAndAgreementAwardWithU.s.DepartmentOfAgricultureForPartnershipsForClimateSmartCommoditiesGrantMember" id="gevo_NoticeOfGrantAndAgreementAwardWithU.s.DepartmentOfAgricultureForPartnershipsForClimateSmartCommoditiesGrantMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="Remarketed2021BondsMember" id="gevo_Remarketed2021BondsMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="RenewableNaturalGasFacilitiesAnnualExpectedOutput" id="gevo_RenewableNaturalGasFacilitiesAnnualExpectedOutput" type="dtr-types:energyItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="GrantFromUsDepartmentOfAgricultureForClimateSmartCommoditiesMember" id="gevo_GrantFromUsDepartmentOfAgricultureForClimateSmartCommoditiesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="GovernmentAssistanceAwardAmountExpectedToBeReimbursed" id="gevo_GovernmentAssistanceAwardAmountExpectedToBeReimbursed" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="GovernmentAssistanceAwardAmountMaximumUtilizationByCompanyForReimbursement" id="gevo_GovernmentAssistanceAwardAmountMaximumUtilizationByCompanyForReimbursement" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="GovernmentAssistanceAwardAmountMaximumUtilizationByThirdPartyForReimbursement" id="gevo_GovernmentAssistanceAwardAmountMaximumUtilizationByThirdPartyForReimbursement" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="ShareBasedCompensationArrangementByShareBasedPaymentAwardOptionsVestedAndExpectedToVestOutstandingWeightedAverageGrantDateFairValue" id="gevo_ShareBasedCompensationArrangementByShareBasedPaymentAwardOptionsVestedAndExpectedToVestOutstandingWeightedAverageGrantDateFairValue" type="dtr-types:perShareItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="CashCollateralForBorrowedSecuritiesReturned" id="gevo_CashCollateralForBorrowedSecuritiesReturned" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="LetterOfCreditAnnualFeesInterestRate" id="gevo_LetterOfCreditAnnualFeesInterestRate" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="RenewableNaturalGasCommodityAndEnvironmentalAttributeRevenueMember" id="gevo_RenewableNaturalGasCommodityAndEnvironmentalAttributeRevenueMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PieceOfOperatingEquipmentMember" id="gevo_PieceOfOperatingEquipmentMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="BiofuelsMember" id="gevo_BiofuelsMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ProceedsFromSaleOfInvestmentTaxCredits" id="gevo_ProceedsFromSaleOfInvestmentTaxCredits" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="PaymentsOfEarnestMoneyDepositsForAssetPurchase" id="gevo_PaymentsOfEarnestMoneyDepositsForAssetPurchase" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="RedTrailEnergyLlcMember" id="gevo_RedTrailEnergyLlcMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AssetAcquisitionPurchasePricePayableForSecuringPostClosingIndemnificationsObligations" id="gevo_AssetAcquisitionPurchasePricePayableForSecuringPostClosingIndemnificationsObligations" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="AssetAcquisitionPurchasePricePayableForSecuringPurchasePriceAdjustments" id="gevo_AssetAcquisitionPurchasePricePayableForSecuringPurchasePriceAdjustments" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="ProceedsFromSaleOfInvestmentTaxCreditsNetOfTransactionFees" id="gevo_ProceedsFromSaleOfInvestmentTaxCreditsNetOfTransactionFees" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DepositsAndOtherAssetsNoncurentEarnestMoneyDepositForAssetPurchase" id="gevo_DepositsAndOtherAssetsNoncurentEarnestMoneyDepositForAssetPurchase" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="InvestmentTaxCreditAssistanceMember" id="gevo_InvestmentTaxCreditAssistanceMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="CultivateAgriculturalIntelligenceLlcMember" id="gevo_CultivateAgriculturalIntelligenceLlcMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AssetAcquisitionRelatedCosts" id="gevo_AssetAcquisitionRelatedCosts" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="NonCashEmployeeBenefitPlanExpense" id="gevo_NonCashEmployeeBenefitPlanExpense" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="IfNetLeverageRatioOfMeasurementPeriodIsLessThan1.5Member" id="gevo_IfNetLeverageRatioOfMeasurementPeriodIsLessThan1.5Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="FinancingReceivableFaceAmount" id="gevo_FinancingReceivableFaceAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="FinancingReceivableInterestRatePercentage" id="gevo_FinancingReceivableInterestRatePercentage" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="IfNetLeverageRatioOfMeasurementPeriodIsGreaterThan1.5AndLessThan3.0Member" id="gevo_IfNetLeverageRatioOfMeasurementPeriodIsGreaterThan1.5AndLessThan3.0Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="IfNetLeverageRatioOfMeasurementPeriodIsGreaterThan3.0Member" id="gevo_IfNetLeverageRatioOfMeasurementPeriodIsGreaterThan3.0Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="OtherRevenueSaleOfIsooctaneAndSoftwareServicesMember" id="gevo_OtherRevenueSaleOfIsooctaneAndSoftwareServicesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="GevoFuelSegmentMember" id="gevo_GevoFuelSegmentMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NumberOfNonvotingObserversToBoardOfInvestee" id="gevo_NumberOfNonvotingObserversToBoardOfInvestee" type="xbrli:integerItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisAssetTransfersLevel1ToLevel2" id="gevo_FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisAssetTransfersLevel1ToLevel2" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisAssetTransfersLevel2ToLevel1" id="gevo_FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisAssetTransfersLevel2ToLevel1" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisLiabilityTransfersLevel1ToLevel2" id="gevo_FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisLiabilityTransfersLevel1ToLevel2" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisLiabilityTransfersLevel2ToLevel1" id="gevo_FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisLiabilityTransfersLevel2ToLevel1" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="AccruedTaxContingencyAmount" id="gevo_AccruedTaxContingencyAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="OperatingLossCarryforwardsNotSubjectedToExpiration" id="gevo_OperatingLossCarryforwardsNotSubjectedToExpiration" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="VariableInterestEntityAbstract" id="gevo_VariableInterestEntityAbstract" type="xbrli:stringItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ChristopherMRyanMember" id="gevo_ChristopherMRyanMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LLynnSmullMember" id="gevo_LLynnSmullMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AndrewLShaferMember" id="gevo_AndrewLShaferMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="KimberlyTBowronMember" id="gevo_KimberlyTBowronMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NetFederalTrueUp" id="gevo_NetFederalTrueUp" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="PlanJuly262024ToJuly252025Member" id="gevo_PlanJuly262024ToJuly252025Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanFebruary172025ToFebruary162026Member" id="gevo_PlanFebruary172025ToFebruary162026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanFebruary262025ToFebruary252026Member" id="gevo_PlanFebruary262025ToFebruary252026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanFebruary202025ToFebruary192026Member" id="gevo_PlanFebruary202025ToFebruary192026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanNovember12024ToOctober312025Member" id="gevo_PlanNovember12024ToOctober312025Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanMarch32025ToMarch42026Member" id="gevo_PlanMarch32025ToMarch42026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LongTermDebtMaturityYearTwoAndAfterYearTwo" id="gevo_LongTermDebtMaturityYearTwoAndAfterYearTwo" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="DeferredTaxAssetsTransactionCosts" id="gevo_DeferredTaxAssetsTransactionCosts" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
</xsd:schema>
