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  <xs:element id="gevo_PlantFacilitiesAndInfrastructureMember" abstract="true" name="PlantFacilitiesAndInfrastructureMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_HighValueProteinProductsMember" abstract="true" name="HighValueProteinProductsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCosts" abstract="false" name="IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_NetZeroSegmentMember" abstract="true" name="NetZeroSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_PowerLetterOfCreditMember" abstract="true" name="PowerLetterOfCreditMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_Series2022AWarrantsMember" abstract="true" name="Series2022AWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_EnvironmentalAttributeInventoryPolicyPolicyTextBlock" abstract="false" name="EnvironmentalAttributeInventoryPolicyPolicyTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
  <xs:element id="gevo_SBALoansMember" abstract="true" name="SBALoansMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DebtInstrumentPercentageOfPrincipalPaymentOnMaturityDate" abstract="false" name="DebtInstrumentPercentageOfPrincipalPaymentOnMaturityDate" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:percentItemType"/>
  <xs:element id="gevo_TaxRefunds" abstract="false" name="TaxRefunds" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_LossContingencyNumberOfIncidents" abstract="false" name="LossContingencyNumberOfIncidents" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_LossContingencyNumberOfDigesters" abstract="false" name="LossContingencyNumberOfDigesters" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_A2021BondsMember" abstract="true" name="A2021BondsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_CornOilMember" abstract="true" name="CornOilMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RenewableNaturalGasMember" abstract="true" name="RenewableNaturalGasMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_June2022OfferingMember" abstract="true" name="June2022OfferingMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_AgriEnergySegmentMember" abstract="true" name="AgriEnergySegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_LakePrestonSouthDakotaMember" abstract="true" name="LakePrestonSouthDakotaMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_FinanceLeaseLiabilityToBePaidAfterYearFour" abstract="false" name="FinanceLeaseLiabilityToBePaidAfterYearFour" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_RenewableNaturalGasSegmentMember" abstract="true" name="RenewableNaturalGasSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_LiabilityClassifiedRestrictedStockAwardsFairValue" abstract="false" name="LiabilityClassifiedRestrictedStockAwardsFairValue" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_NumberOfDigesterSites" abstract="false" name="NumberOfDigesterSites" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_NatureOfBusinessFinancialConditionAndBasisOfPresentationTable" abstract="true" name="NatureOfBusinessFinancialConditionAndBasisOfPresentationTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType"/>
  <xs:element id="gevo_EarningsPerShareDilutedIncreaseDecrease" abstract="false" name="EarningsPerShareDilutedIncreaseDecrease" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:perShareItemType"/>
  <xs:element id="gevo_BondLetterOfCreditMember" abstract="true" name="BondLetterOfCreditMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_StockIssuedDuringPeriodValuesWarrantsExercised" abstract="false" name="StockIssuedDuringPeriodValuesWarrantsExercised" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsTextBlock" abstract="false" name="DepositsAndOtherAssetsTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
  <xs:element id="gevo_StockIncentivePlan2010Member" abstract="true" name="StockIncentivePlan2010Member" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RenewableNaturalGasSuppliesNumberOfDairies" abstract="false" name="RenewableNaturalGasSuppliesNumberOfDairies" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_LuverneMinnesotaMember" abstract="true" name="LuverneMinnesotaMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsNoncurrent" abstract="false" name="DepositsAndOtherAssetsNoncurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_JetFuelMember" abstract="true" name="JetFuelMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_CashFlowLesseeAbstract" abstract="true" name="CashFlowLesseeAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_ProjectProductionCapacityPoundPerYear" abstract="false" name="ProjectProductionCapacityPoundPerYear" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:massItemType"/>
  <xs:element id="gevo_SAFIsooctaneIsoocteneAndOtherMember" abstract="true" name="SAFIsooctaneIsoocteneAndOtherMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_GevoSegmentMember" abstract="true" name="GevoSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsLineItems" abstract="true" name="DepositsAndOtherAssetsLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_SaleOfStockAuthorizedAmount" abstract="false" name="SaleOfStockAuthorizedAmount" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_StockIssuedDuringPeriodSharesWarrantsExercised" abstract="false" name="StockIssuedDuringPeriodSharesWarrantsExercised" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="gevo_SeriesKWarrantsMember" abstract="true" name="SeriesKWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCostsInShares" abstract="false" name="IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCostsInShares" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="gevo_PaymentsToAcquirePatentsAndLicense" abstract="false" name="PaymentsToAcquirePatentsAndLicense" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsNoncurrentDepositsReceivableFullyReimbursedUponCompletion" abstract="false" name="DepositsAndOtherAssetsNoncurrentDepositsReceivableFullyReimbursedUponCompletion" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsNoncurrentDepositsReceivable" abstract="false" name="DepositsAndOtherAssetsNoncurrentDepositsReceivable" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_CommonSharesIssuedUponExerciseOfWarrants" abstract="false" name="CommonSharesIssuedUponExerciseOfWarrants" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="gevo_CashPaidForInterestCapitalizedToConstructionInProgress" abstract="false" name="CashPaidForInterestCapitalizedToConstructionInProgress" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_EnvironmentalAttributesMember" abstract="true" name="EnvironmentalAttributesMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_EarningsPerShareBasicIncreaseDecrease" abstract="false" name="EarningsPerShareBasicIncreaseDecrease" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:perShareItemType"/>
  <xs:element id="gevo_RenewableNaturalGasCommodityMember" abstract="true" name="RenewableNaturalGasCommodityMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_CollaborativeArrangementAdvancedDevelopmentFeePaymentsCommitted" abstract="false" name="CollaborativeArrangementAdvancedDevelopmentFeePaymentsCommitted" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_PrepaidEngineering" abstract="false" name="PrepaidEngineering" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_CollaborativeArrangementPayment" abstract="false" name="CollaborativeArrangementPayment" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_DebtSecuritiesAvailableForSaleCurrentAccumulatedGrossUnrealizedLossBeforeTax" abstract="false" name="DebtSecuritiesAvailableForSaleCurrentAccumulatedGrossUnrealizedLossBeforeTax" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_ScheduleOfEquityIncentivePlansLineItems" abstract="true" name="ScheduleOfEquityIncentivePlansLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_CollaborativeArrangementDevelopmentChargesCommittedToPay" abstract="false" name="CollaborativeArrangementDevelopmentChargesCommittedToPay" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_DevelopmentAgreementWithJuhlMember" abstract="true" name="DevelopmentAgreementWithJuhlMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_ProjectProductionCapacityVolumePerYear" abstract="false" name="ProjectProductionCapacityVolumePerYear" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:volumeItemType"/>
  <xs:element id="gevo_LiabilityClassifiedAwardsMember" abstract="true" name="LiabilityClassifiedAwardsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_ElectricityAboveUseEstimatedMember" abstract="true" name="ElectricityAboveUseEstimatedMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_PreliminaryStageProjectCosts" abstract="false" name="PreliminaryStageProjectCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_EquipmentLoansMember" abstract="true" name="EquipmentLoansMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_IndemnificationLiabilities" abstract="false" name="IndemnificationLiabilities" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_EnzymesAndOtherInputsMember" abstract="true" name="EnzymesAndOtherInputsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_EthanolSalesAndRelatedProductsMember" abstract="true" name="EthanolSalesAndRelatedProductsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_InventoryEnvironmentalAttributesNetOfReserves" abstract="false" name="InventoryEnvironmentalAttributesNetOfReserves" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_EquityClassifiedAwardsMember" abstract="true" name="EquityClassifiedAwardsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RenewableEnergyCreditsMember" abstract="true" name="RenewableEnergyCreditsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsTableTextBlock" abstract="false" name="DepositsAndOtherAssetsTableTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
  <xs:element id="gevo_CollaborativeArrangementDevelopmentChargesCommittedUponCompletion" abstract="false" name="CollaborativeArrangementDevelopmentChargesCommittedUponCompletion" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_PaymentsForNetSettlementOfCommonStockUnderStockPlans" abstract="false" name="PaymentsForNetSettlementOfCommonStockUnderStockPlans" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisedInPeriodWeightedAverageGrantDateFairValue" abstract="false" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisedInPeriodWeightedAverageGrantDateFairValue" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:perShareItemType"/>
</xs:schema>
