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  <xsd:element name="WarrantsExercised" id="gevo_WarrantsExercised" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="NumberOfLongTermFuelSupplyContracts" id="gevo_NumberOfLongTermFuelSupplyContracts" type="xbrli:integerItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="DefinedContributionPlanEmployerAccruedMatchingContributions" id="gevo_DefinedContributionPlanEmployerAccruedMatchingContributions" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="AggregateOfferingPrice" id="gevo_AggregateOfferingPrice" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="TradeAccountsReceivableNetMember" id="gevo_TradeAccountsReceivableNetMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="CustomerOneMember" id="gevo_CustomerOneMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="Remarketed2021BondsMember" id="gevo_Remarketed2021BondsMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="RenewableNaturalGasFacilitiesAnnualExpectedOutput" id="gevo_RenewableNaturalGasFacilitiesAnnualExpectedOutput" type="dtr-types:energyItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="ShareBasedCompensationArrangementByShareBasedPaymentAwardOptionsVestedAndExpectedToVestOutstandingWeightedAverageGrantDateFairValue" id="gevo_ShareBasedCompensationArrangementByShareBasedPaymentAwardOptionsVestedAndExpectedToVestOutstandingWeightedAverageGrantDateFairValue" type="dtr-types:perShareItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="BiofuelsMember" id="gevo_BiofuelsMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ProceedsFromSaleOfInvestmentTaxCredits" id="gevo_ProceedsFromSaleOfInvestmentTaxCredits" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="PaymentsOfEarnestMoneyDepositsForAssetPurchase" id="gevo_PaymentsOfEarnestMoneyDepositsForAssetPurchase" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="RedTrailEnergyLlcMember" id="gevo_RedTrailEnergyLlcMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ProceedsFromSaleOfInvestmentTaxCreditsNetOfTransactionFees" id="gevo_ProceedsFromSaleOfInvestmentTaxCreditsNetOfTransactionFees" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DepreciationCapitalizedToInventory" id="gevo_DepreciationCapitalizedToInventory" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="InvestmentTaxCreditAssistanceMember" id="gevo_InvestmentTaxCreditAssistanceMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="CultivateAgriculturalIntelligenceLlcMember" id="gevo_CultivateAgriculturalIntelligenceLlcMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DepreciationExpenseFromSaleOfInventory" id="gevo_DepreciationExpenseFromSaleOfInventory" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="AssetAcquisitionRelatedCosts" id="gevo_AssetAcquisitionRelatedCosts" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="IfNetLeverageRatioOfMeasurementPeriodIsLessThan1.5Member" id="gevo_IfNetLeverageRatioOfMeasurementPeriodIsLessThan1.5Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="IfNetLeverageRatioOfMeasurementPeriodIsGreaterThan1.5AndLessThan3.0Member" id="gevo_IfNetLeverageRatioOfMeasurementPeriodIsGreaterThan1.5AndLessThan3.0Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="IfNetLeverageRatioOfMeasurementPeriodIsGreaterThan3.0Member" id="gevo_IfNetLeverageRatioOfMeasurementPeriodIsGreaterThan3.0Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="OtherRevenueSaleOfIsooctaneAndSoftwareServicesMember" id="gevo_OtherRevenueSaleOfIsooctaneAndSoftwareServicesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="GevoFuelSegmentMember" id="gevo_GevoFuelSegmentMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisAssetTransfersLevel1ToLevel2" id="gevo_FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisAssetTransfersLevel1ToLevel2" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisAssetTransfersLevel2ToLevel1" id="gevo_FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisAssetTransfersLevel2ToLevel1" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisLiabilityTransfersLevel1ToLevel2" id="gevo_FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisLiabilityTransfersLevel1ToLevel2" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisLiabilityTransfersLevel2ToLevel1" id="gevo_FairValueMeasurementWithUnobservableInputsReconciliationRecurringBasisLiabilityTransfersLevel2ToLevel1" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="AccruedTaxContingencyAmount" id="gevo_AccruedTaxContingencyAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="OperatingLossCarryforwardsNotSubjectedToExpiration" id="gevo_OperatingLossCarryforwardsNotSubjectedToExpiration" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="VariableInterestEntityAbstract" id="gevo_VariableInterestEntityAbstract" type="xbrli:stringItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DeferredTaxAssetsTransactionCosts" id="gevo_DeferredTaxAssetsTransactionCosts" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="RedeemableNoncontrollingInterestPolicyPolicyTextBlock" id="gevo_RedeemableNoncontrollingInterestPolicyPolicyTextBlock" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="EthanolRelatedProductsMember" id="gevo_EthanolRelatedProductsMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="BusinessCombinationRecognizedIdentifiableAssetsAcquiredAndLiabilitiesAssumedRightOfUseAssets" id="gevo_BusinessCombinationRecognizedIdentifiableAssetsAcquiredAndLiabilitiesAssumedRightOfUseAssets" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="BusinessCombinationRecognizedIdentifiableAssetsAcquiredAndLiabilitiesAssumedCurrentLiabilitiesAccountsPayableAndAccruedLiabilities" id="gevo_BusinessCombinationRecognizedIdentifiableAssetsAcquiredAndLiabilitiesAssumedCurrentLiabilitiesAccountsPayableAndAccruedLiabilities" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="BusinessCombinationRecognizedIdentifiableAssetAcquiredAndLiabilityAssumedLeaseObligationCurrent" id="gevo_BusinessCombinationRecognizedIdentifiableAssetAcquiredAndLiabilityAssumedLeaseObligationCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="BusinessCombinationRecognizedIdentifiableAssetAcquiredAndLiabilityAssumedLeaseObligationNoncurrent" id="gevo_BusinessCombinationRecognizedIdentifiableAssetAcquiredAndLiabilityAssumedLeaseObligationNoncurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="BusinessCombinationRecognizedIdentifiableAssetsAcquiredAndLiabilitiesAssumedAssetRetirementObligationNoncurrent" id="gevo_BusinessCombinationRecognizedIdentifiableAssetsAcquiredAndLiabilitiesAssumedAssetRetirementObligationNoncurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="BusinessCombinationConsiderationTransferredNetOfAdjustments" id="gevo_BusinessCombinationConsiderationTransferredNetOfAdjustments" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="AssetRetirementObligationLiabilitiesAssumed" id="gevo_AssetRetirementObligationLiabilitiesAssumed" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="SeniorSecuredTermLoanMember" id="gevo_SeniorSecuredTermLoanMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LeverageRatioMeasurementPeriodNumberOfFiscalQuarters" id="gevo_LeverageRatioMeasurementPeriodNumberOfFiscalQuarters" type="xbrli:integerItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="LeverageRatio" id="gevo_LeverageRatio" type="xbrli:pureItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="NumberOfNonvotingObserversToBeAppointedByLender" id="gevo_NumberOfNonvotingObserversToBeAppointedByLender" type="xbrli:integerItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="DebtInstrumentRefinancedAmount" id="gevo_DebtInstrumentRefinancedAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="EastRiverCommitmentMember" id="gevo_EastRiverCommitmentMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="WaterPurchasesMember" id="gevo_WaterPurchasesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="FirmPurchaseCommitmentsForCornMember" id="gevo_FirmPurchaseCommitmentsForCornMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="FairValueAdjustmentsOfRedeemableNoncontrollingInterest" id="gevo_FairValueAdjustmentsOfRedeemableNoncontrollingInterest" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="GevoNorthDakotaSegmentMember" id="gevo_GevoNorthDakotaSegmentMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LowCarbonEthanolMember" id="gevo_LowCarbonEthanolMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="EthanolProcessCapacityVolumePerYear" id="gevo_EthanolProcessCapacityVolumePerYear" type="dtr-types:volumeItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="CornFiberEthanolMember" id="gevo_CornFiberEthanolMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LowCarbonAnimalFeedAndVegetableOilMember" id="gevo_LowCarbonAnimalFeedAndVegetableOilMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="MinimumProductionCapacityInTons" id="gevo_MinimumProductionCapacityInTons" type="dtr-types:massItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="AnnualCapacityForDisposalOrRecycleOfCarbonDioxideInTons" id="gevo_AnnualCapacityForDisposalOrRecycleOfCarbonDioxideInTons" type="dtr-types:massItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="MaximumCleanFuelProductionCreditsAvailableUnderRightOfFirstOffer" id="gevo_MaximumCleanFuelProductionCreditsAvailableUnderRightOfFirstOffer" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="CommonStockIncreaseInCapitalSharesReservedForFutureIssuance" id="gevo_CommonStockIncreaseInCapitalSharesReservedForFutureIssuance" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="RestrictedCashReleasedToCashAndCashEquivalents" id="gevo_RestrictedCashReleasedToCashAndCashEquivalents" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="AgriEnergyLlcMember" id="gevo_AgriEnergyLlcMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="RestrictedCashReleased" id="gevo_RestrictedCashReleased" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DebtServiceReserve" id="gevo_DebtServiceReserve" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="OperatingAndMaintenanceReserve" id="gevo_OperatingAndMaintenanceReserve" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="TaxCreditsMember" id="gevo_TaxCreditsMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DepositsAndOtherAssetsNoncurrentEarnestMoneyDepositForAssetPurchase" id="gevo_DepositsAndOtherAssetsNoncurrentEarnestMoneyDepositForAssetPurchase" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="IssuanceOfNoncontrollingInterest" id="gevo_IssuanceOfNoncontrollingInterest" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="TransferAgreementToTransferCreditsThresholdPercentage" id="gevo_TransferAgreementToTransferCreditsThresholdPercentage" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="TransferAgreementToTransferCreditsPerCreditFee" id="gevo_TransferAgreementToTransferCreditsPerCreditFee" type="srt-types:perUnitItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="PlanJuly262024ToJuly252025Member" id="gevo_PlanJuly262024ToJuly252025Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanFebruary172025ToFebruary162026Member" id="gevo_PlanFebruary172025ToFebruary162026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanFebruary262025ToFebruary252026Member" id="gevo_PlanFebruary262025ToFebruary252026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanFebruary202025ToFebruary192026Member" id="gevo_PlanFebruary202025ToFebruary192026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanNovember12024ToOctober312025Member" id="gevo_PlanNovember12024ToOctober312025Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanMarch32025ToMarch42026Member" id="gevo_PlanMarch32025ToMarch42026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanMarch72025ToMarch62026Member" id="gevo_PlanMarch72025ToMarch62026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanMay232025ToMay222026Member" id="gevo_PlanMay232025ToMay222026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PatrickR.GruberMember" id="gevo_PatrickR.GruberMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ChristopherM.RyanMember" id="gevo_ChristopherM.RyanMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="L.LynnSmullMember" id="gevo_L.LynnSmullMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PaulD.BloomMember" id="gevo_PaulD.BloomMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AndrewL.ShaferMember" id="gevo_AndrewL.ShaferMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="KimberlyT.BowronMember" id="gevo_KimberlyT.BowronMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AngeloAmorelliMember" id="gevo_AngeloAmorelliMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="GaryW.MizeMember" id="gevo_GaryW.MizeMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanNovember252025ToNovember242026Member" id="gevo_PlanNovember252025ToNovember242026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AmortizationOfDeferredFinancingCosts" id="gevo_AmortizationOfDeferredFinancingCosts" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="AnnualInjectionCapacityForWells" id="gevo_AnnualInjectionCapacityForWells" type="dtr-types:massItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="AdditionalAnnualInjectionCapacityForWellsFromLeases" id="gevo_AdditionalAnnualInjectionCapacityForWellsFromLeases" type="dtr-types:massItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="TwentyTwentyFiveBondsMember" id="gevo_TwentyTwentyFiveBondsMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DebtServiceReserveAndOperatingAndMaintenanceReserve" id="gevo_DebtServiceReserveAndOperatingAndMaintenanceReserve" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="TermLoanOneMember" id="gevo_TermLoanOneMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ProceedsFromIssuanceOfBonds" id="gevo_ProceedsFromIssuanceOfBonds" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="RepaymentsOfBonds" id="gevo_RepaymentsOfBonds" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="TermLoanTwoMember" id="gevo_TermLoanTwoMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DisposalGroupIncludingDiscontinuedOperationConsiderationCash" id="gevo_DisposalGroupIncludingDiscontinuedOperationConsiderationCash" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DisposalGroupIncludingDiscontinuedOperationConsiderationNoteReceivable" id="gevo_DisposalGroupIncludingDiscontinuedOperationConsiderationNoteReceivable" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="TaxCreditPolicyPolicyTextBlock" id="gevo_TaxCreditPolicyPolicyTextBlock" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="PlanMarch232026ToMarch222027Member" id="gevo_PlanMarch232026ToMarch222027Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanFebruary262026ToFebruary252027Member" id="gevo_PlanFebruary262026ToFebruary252027Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanFebruary202026ToFebruary192027Member" id="gevo_PlanFebruary202026ToFebruary192027Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanMarch32026ToMarch42027Member" id="gevo_PlanMarch32026ToMarch42027Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PlanMarch12026ToFebruary282027Member" id="gevo_PlanMarch12026ToFebruary282027Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="OluwagbemilekeYAgiriMember" id="gevo_OluwagbemilekeYAgiriMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LindsayC.FitzgeraldMember" id="gevo_LindsayC.FitzgeraldMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LeaseDisclosureTextBlock" id="gevo_LeaseDisclosureTextBlock" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="NotesReceivableDiscount" id="gevo_NotesReceivableDiscount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DisposalGroupAnnualProductionCapacity" id="gevo_DisposalGroupAnnualProductionCapacity" type="dtr-types:volumeItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="NotesReceivableAnnualPrincipalPayment" id="gevo_NotesReceivableAnnualPrincipalPayment" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DisposalGroupIncludingDiscontinuedOperationConsiderationNoteReceivableNetOfDiscount" id="gevo_DisposalGroupIncludingDiscontinuedOperationConsiderationNoteReceivableNetOfDiscount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DisposalGroupIncludingDiscontinuedOperationConsiderationFairValue" id="gevo_DisposalGroupIncludingDiscontinuedOperationConsiderationFairValue" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DisposalGroupIncludingDiscontinuedOperationLand" id="gevo_DisposalGroupIncludingDiscontinuedOperationLand" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DisposalGroupNotDiscontinuedOperationTransactionCosts" id="gevo_DisposalGroupNotDiscontinuedOperationTransactionCosts" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DebtInstrumentRedemptionPremiumAmount" id="gevo_DebtInstrumentRedemptionPremiumAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="CleanFuelProductionCreditsGenerated" id="gevo_CleanFuelProductionCreditsGenerated" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="CleanFuelProductionCreditsPerUnit" id="gevo_CleanFuelProductionCreditsPerUnit" type="srt-types:perUnitItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="TransferAgreementToTransferCreditsUnderDeliveryFees" id="gevo_TransferAgreementToTransferCreditsUnderDeliveryFees" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="TaxCreditTransferAgreementNumberOfTranches" id="gevo_TaxCreditTransferAgreementNumberOfTranches" type="xbrli:integerItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="ProceedsFromCleanFuelProductionCredits" id="gevo_ProceedsFromCleanFuelProductionCredits" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="PrepaidInsuranceNonCurrent" id="gevo_PrepaidInsuranceNonCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="ImprovementsOnAssetsOwnedByOthers" id="gevo_ImprovementsOnAssetsOwnedByOthers" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DebtIssuanceCosts" id="gevo_DebtIssuanceCosts" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="EffectiveIncomeTaxRateReconciliationNondeductibleExpenseOfficersCompensationAmount" id="gevo_EffectiveIncomeTaxRateReconciliationNondeductibleExpenseOfficersCompensationAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="EffectiveIncomeTaxRateReconciliationNetFederalTrueUpsAmount" id="gevo_EffectiveIncomeTaxRateReconciliationNetFederalTrueUpsAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="EffectiveIncomeTaxRateReconciliationNondeductibleExpenseOfficersCompensationPercent" id="gevo_EffectiveIncomeTaxRateReconciliationNondeductibleExpenseOfficersCompensationPercent" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="EffectiveIncomeTaxRateReconciliationNetFederalTrueUpsPercent" id="gevo_EffectiveIncomeTaxRateReconciliationNetFederalTrueUpsPercent" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="DeferredTaxAssetValuationAllowanceRollForward" id="gevo_DeferredTaxAssetValuationAllowanceRollForward" type="xbrli:stringItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="DeferredTaxAssetsDeferredPartnershipInterests" id="gevo_DeferredTaxAssetsDeferredPartnershipInterests" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="TransferAgreementToTransferCreditsThresholdAmount" id="gevo_TransferAgreementToTransferCreditsThresholdAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="ProceedsFromWithdrawalOnBorrowerSRevenueAccount" id="gevo_ProceedsFromWithdrawalOnBorrowerSRevenueAccount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DebtInstrumentRedemptionPricePremiumPercentage" id="gevo_DebtInstrumentRedemptionPricePremiumPercentage" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="GevoNorthDakotaReportingUnitMember" id="gevo_GevoNorthDakotaReportingUnitMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="SoftwareAndServicesReportingUnitMember" id="gevo_SoftwareAndServicesReportingUnitMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DeferredTaxLiabilitiesOperatingLeaseAssets" id="gevo_DeferredTaxLiabilitiesOperatingLeaseAssets" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="GevoReportingUnitMember" id="gevo_GevoReportingUnitMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LesseeOperatingLeaseNumberOfOptionsToExtend" id="gevo_LesseeOperatingLeaseNumberOfOptionsToExtend" type="xbrli:integerItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="LesseeOperatingLeaseTerminationNoticePeriod" id="gevo_LesseeOperatingLeaseTerminationNoticePeriod" type="xbrli:durationItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="LeaseAmortization" id="gevo_LeaseAmortization" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
</xsd:schema>
