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  <xs:element id="gevo_DepositsAndOtherAssetsNoncurrentEquityInterest" abstract="false" name="DepositsAndOtherAssetsNoncurrentEquityInterest" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_CommonSharesIssuedUponExerciseOfWarrants" abstract="false" name="CommonSharesIssuedUponExerciseOfWarrants" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="gevo_CollaborativeArrangementOneTimeSystemDevelopmentCharge" abstract="false" name="CollaborativeArrangementOneTimeSystemDevelopmentCharge" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_JuhlMember" abstract="true" name="JuhlMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_FinanceLeaseLiabilityToBePaidAfterYearFour" abstract="false" name="FinanceLeaseLiabilityToBePaidAfterYearFour" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_AccountsPayableAndAccruedLiabilitiesTable" abstract="true" name="AccountsPayableAndAccruedLiabilitiesTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType"/>
  <xs:element id="gevo_ElectricityAboveUseEstimatedMember" abstract="true" name="ElectricityAboveUseEstimatedMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RestrictedCashAndCashEquivalentsInterestPaidOnBonds" abstract="false" name="RestrictedCashAndCashEquivalentsInterestPaidOnBonds" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_RenewableNaturalGasSegmentMember" abstract="true" name="RenewableNaturalGasSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RestrictedCashAndCashEquivalentsInterestIncome" abstract="false" name="RestrictedCashAndCashEquivalentsInterestIncome" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_AgriEnergyMember" abstract="true" name="AgriEnergyMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DebtSecuritiesAvailableForSaleNoncurrentAccumulatedGrossUnrealizedLossBeforeTax" abstract="false" name="DebtSecuritiesAvailableForSaleNoncurrentAccumulatedGrossUnrealizedLossBeforeTax" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_ScheduleOfEquityIncentivePlansLineItems" abstract="true" name="ScheduleOfEquityIncentivePlansLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_CollaborativeArrangementPercentageOfSecondPaymentDuePeriodFollowingExecution" abstract="false" name="CollaborativeArrangementPercentageOfSecondPaymentDuePeriodFollowingExecution" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:durationItemType"/>
  <xs:element id="gevo_ProceedsFromIssuanceOfBondsUsed" abstract="false" name="ProceedsFromIssuanceOfBondsUsed" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_RestrictedCashAndCashEquivalentsRestrictedCashForCollateral" abstract="false" name="RestrictedCashAndCashEquivalentsRestrictedCashForCollateral" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_StockIncentivePlan2010Member" abstract="true" name="StockIncentivePlan2010Member" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RestrictedStockLiabilityClassifiedAwardsMember" abstract="true" name="RestrictedStockLiabilityClassifiedAwardsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RenewableNaturalGasSuppliesNumberAdditionalOfMilkingCowsExpected" abstract="false" name="RenewableNaturalGasSuppliesNumberAdditionalOfMilkingCowsExpected" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_CommitmentCollateralPercentageOfRenewableEnergyCredits" abstract="false" name="CommitmentCollateralPercentageOfRenewableEnergyCredits" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:percentItemType"/>
  <xs:element id="gevo_RenewableNaturalGasSuppliesNumberOfDairies" abstract="false" name="RenewableNaturalGasSuppliesNumberOfDairies" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_StockIssuedDuringPeriodSharesWarrantsExercised" abstract="false" name="StockIssuedDuringPeriodSharesWarrantsExercised" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="gevo_Series2020AWarrantsMember" abstract="true" name="Series2020AWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_EmployeeStockPurchasePlanMember" abstract="true" name="EmployeeStockPurchasePlanMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_LakePrestonSouthDakotaMember" abstract="true" name="LakePrestonSouthDakotaMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RestrictedCashAndCashEquivalentsBondProceeds" abstract="false" name="RestrictedCashAndCashEquivalentsBondProceeds" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_SeriesKWarrantsMember" abstract="true" name="SeriesKWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_TaxRefunds" abstract="false" name="TaxRefunds" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_EquipmentLoansMember" abstract="true" name="EquipmentLoansMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisedInPeriodWeightedAverageGrantDateFairValue" abstract="false" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisedInPeriodWeightedAverageGrantDateFairValue" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:perShareItemType"/>
  <xs:element id="gevo_PaymentOfFinanceLeaseLiabilities" abstract="false" name="PaymentOfFinanceLeaseLiabilities" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsLineItems" abstract="true" name="DepositsAndOtherAssetsLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCosts" abstract="false" name="IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_PreliminaryStageProjectCosts" abstract="false" name="PreliminaryStageProjectCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCostsInShares" abstract="false" name="IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCostsInShares" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="gevo_CornMember" abstract="true" name="CornMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_FiniteLivedIntangibleAssetExpectedAmortizationAfterYearFour" abstract="false" name="FiniteLivedIntangibleAssetExpectedAmortizationAfterYearFour" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_CollaborativeArrangementPercentageOfSecondPaymentDue" abstract="false" name="CollaborativeArrangementPercentageOfSecondPaymentDue" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:percentItemType"/>
  <xs:element id="gevo_June2022OfferingMember" abstract="true" name="June2022OfferingMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_NatureOfBusinessFinancialConditionAndBasisOfPresentationTable" abstract="true" name="NatureOfBusinessFinancialConditionAndBasisOfPresentationTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType"/>
  <xs:element id="gevo_PreliminaryStageProjectsMember" abstract="true" name="PreliminaryStageProjectsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_AccountsPayableAndAccruedLiabilitiesLineItems" abstract="true" name="AccountsPayableAndAccruedLiabilitiesLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsNoncurrent" abstract="false" name="DepositsAndOtherAssetsNoncurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_CashFlowLesseeAbstract" abstract="true" name="CashFlowLesseeAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="gevo_EquityClassifiedAwardsMember" abstract="true" name="EquityClassifiedAwardsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_LesseeOperatingLeaseLiabilityToBePaidAfterYearFour" abstract="false" name="LesseeOperatingLeaseLiabilityToBePaidAfterYearFour" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_IndemnificationLiabilities" abstract="false" name="IndemnificationLiabilities" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_EthanolMember" abstract="true" name="EthanolMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_PalladiumMember" abstract="true" name="PalladiumMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_PaymentsForNetSettlementOfCommonStockUnderStockPlans" abstract="false" name="PaymentsForNetSettlementOfCommonStockUnderStockPlans" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_PaymentsToAcquireIntangibleAssetsPlantPropertyAndEquipment" abstract="false" name="PaymentsToAcquireIntangibleAssetsPlantPropertyAndEquipment" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_GevoMember" abstract="true" name="GevoMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_IsobutanolMember" abstract="true" name="IsobutanolMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_NumberOfDigesterSites" abstract="false" name="NumberOfDigesterSites" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_NonqualifiedStockOptionsMember" abstract="true" name="NonqualifiedStockOptionsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_RenewableEnergyCreditsMember" abstract="true" name="RenewableEnergyCreditsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_GevoSegmentMember" abstract="true" name="GevoSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_GainLossFromChangeInFairValueOfDerivativeWarrantLiability" abstract="false" name="GainLossFromChangeInFairValueOfDerivativeWarrantLiability" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_ScheduleOfEquityIncentivePlansTable" abstract="true" name="ScheduleOfEquityIncentivePlansTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType"/>
  <xs:element id="gevo_LossContingencyNumberOfIncidents" abstract="false" name="LossContingencyNumberOfIncidents" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsTextBlock" abstract="false" name="DepositsAndOtherAssetsTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
  <xs:element id="gevo_SBALoansMember" abstract="true" name="SBALoansMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="gevo_DepositsAndOtherAssetsNoncurrentExclusivityFees" abstract="false" name="DepositsAndOtherAssetsNoncurrentExclusivityFees" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="gevo_SaleOfStockRemainingCapacityAvailableAmount" abstract="false" name="SaleOfStockRemainingCapacityAvailableAmount" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
</xs:schema>
