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  <xsd:element id="gevo_CollaborativeArrangementAdvancedDevelopmentFeePaymentsCommitted" abstract="false" name="CollaborativeArrangementAdvancedDevelopmentFeePaymentsCommitted" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsTableTextBlock" abstract="false" name="DepositsAndOtherAssetsTableTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType" />
  <xsd:element id="gevo_DevelopmentAgreementWithJuhlMember" abstract="true" name="DevelopmentAgreementWithJuhlMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_StockIncentivePlan2010Member" abstract="true" name="StockIncentivePlan2010Member" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_RenewableNaturalGasSegmentMember" abstract="true" name="RenewableNaturalGasSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_RenewableEnergyCreditsMember" abstract="true" name="RenewableEnergyCreditsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_LiabilityClassifiedAwardsMember" abstract="true" name="LiabilityClassifiedAwardsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_CommitmentAxis" abstract="true" name="CommitmentAxis" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:dimensionItem" type="xbrli:stringItemType" />
  <xsd:element id="gevo_BondLetterOfCreditMember" abstract="true" name="BondLetterOfCreditMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_SaleOfStockRemainingCapacityAvailableAmount" abstract="false" name="SaleOfStockRemainingCapacityAvailableAmount" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DebtInstrumentPercentageOfPrincipalPaymentOnMaturityDate" abstract="false" name="DebtInstrumentPercentageOfPrincipalPaymentOnMaturityDate" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:percentItemType" />
  <xsd:element id="gevo_PowerLetterOfCreditMember" abstract="true" name="PowerLetterOfCreditMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_AccountsPayableAndAccruedLiabilitiesTable" abstract="true" name="AccountsPayableAndAccruedLiabilitiesTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType" />
  <xsd:element id="gevo_PrepaidFeedstockNoncurrent" abstract="false" name="PrepaidFeedstockNoncurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_CashFlowLesseeAbstract" abstract="true" name="CashFlowLesseeAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType" />
  <xsd:element id="gevo_HydrocarbonMember" abstract="true" name="HydrocarbonMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_Series2022AWarrantsMember" abstract="true" name="Series2022AWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_PrajCommitmentMember" abstract="true" name="PrajCommitmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_AgriEnergySegmentMember" abstract="true" name="AgriEnergySegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_DefensiveAssetsMember" abstract="true" name="DefensiveAssetsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_SBALoansMember" abstract="true" name="SBALoansMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_ProjectProductionCapacityVolumePerYear" abstract="false" name="ProjectProductionCapacityVolumePerYear" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:volumeItemType" />
  <xsd:element id="gevo_IdleFacilityCosts" abstract="false" name="IdleFacilityCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentExclusivityFees" abstract="false" name="DepositsAndOtherAssetsNoncurrentExclusivityFees" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_Zero6CommitmentMember" abstract="true" name="Zero6CommitmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_AccountsPayableAndAccruedLiabilitiesLineItems" abstract="true" name="AccountsPayableAndAccruedLiabilitiesLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType" />
  <xsd:element id="gevo_StockIssuedDuringPeriodSharesWarrantsExercised" abstract="false" name="StockIssuedDuringPeriodSharesWarrantsExercised" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:sharesItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentDepositsReceivableReimbursedOrUsedAsInvestment" abstract="false" name="DepositsAndOtherAssetsNoncurrentDepositsReceivableReimbursedOrUsedAsInvestment" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_CommitmentDomain" abstract="true" name="CommitmentDomain" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_GevoSegmentMember" abstract="true" name="GevoSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_LakePrestonSouthDakotaMember" abstract="true" name="LakePrestonSouthDakotaMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_CollaborativeArrangementDevelopmentChargesCommittedUponCompletion" abstract="false" name="CollaborativeArrangementDevelopmentChargesCommittedUponCompletion" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_NetZeroSegmentMember" abstract="true" name="NetZeroSegmentMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentOtherAssetsNet" abstract="false" name="DepositsAndOtherAssetsNoncurrentOtherAssetsNet" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisedInPeriodWeightedAverageGrantDateFairValue" abstract="false" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisedInPeriodWeightedAverageGrantDateFairValue" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:perShareItemType" />
  <xsd:element id="gevo_RenewableNaturalGasSuppliesNumberOfDairies" abstract="false" name="RenewableNaturalGasSuppliesNumberOfDairies" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType" />
  <xsd:element id="gevo_SAFIsooctaneIsoocteneAndOtherMember" abstract="true" name="SAFIsooctaneIsoocteneAndOtherMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_CollaborativeArrangementDevelopmentChargesCommittedToPay" abstract="false" name="CollaborativeArrangementDevelopmentChargesCommittedToPay" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentEquityInterest" abstract="false" name="DepositsAndOtherAssetsNoncurrentEquityInterest" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_LuverneMinnesotaMember" abstract="true" name="LuverneMinnesotaMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_CollaborativeArrangementReimbursableCosts" abstract="false" name="CollaborativeArrangementReimbursableCosts" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_EnvironmentalAttributesMember" abstract="true" name="EnvironmentalAttributesMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_CommonSharesIssuedUponExerciseOfWarrants" abstract="false" name="CommonSharesIssuedUponExerciseOfWarrants" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:sharesItemType" />
  <xsd:element id="gevo_PurchaseObligationToBePaidAfterYearFour" abstract="false" name="PurchaseObligationToBePaidAfterYearFour" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_NumberOfLongTermFuelSupplyContracts" abstract="false" name="NumberOfLongTermFuelSupplyContracts" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType" />
  <xsd:element id="gevo_ElectricityAboveUseEstimatedMember" abstract="true" name="ElectricityAboveUseEstimatedMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_EquipmentLoansMember" abstract="true" name="EquipmentLoansMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_CornOilMember" abstract="true" name="CornOilMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_JetFuelMember" abstract="true" name="JetFuelMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_FinanceLeaseLiabilityToBePaidAfterYearFour" abstract="false" name="FinanceLeaseLiabilityToBePaidAfterYearFour" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_NatureOfBusinessFinancialConditionAndBasisOfPresentationLineItems" abstract="true" name="NatureOfBusinessFinancialConditionAndBasisOfPresentationLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType" />
  <xsd:element id="gevo_DepositsAndOtherAssetsNoncurrentDepositsReceivableFullyReimbursedUponCompletion" abstract="false" name="DepositsAndOtherAssetsNoncurrentDepositsReceivableFullyReimbursedUponCompletion" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_CommitmentCollateralPercentageOfRenewableEnergyCredits" abstract="false" name="CommitmentCollateralPercentageOfRenewableEnergyCredits" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:percentItemType" />
  <xsd:element id="gevo_SeriesKWarrantsMember" abstract="true" name="SeriesKWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_LesseeOperatingLeaseLiabilityToBePaidAfterYearFour" abstract="false" name="LesseeOperatingLeaseLiabilityToBePaidAfterYearFour" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" />
  <xsd:element id="gevo_ScheduleOfEquityIncentivePlansLineItems" abstract="true" name="ScheduleOfEquityIncentivePlansLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType" />
  <xsd:element id="gevo_PlantFacilitiesAndInfrastructureMember" abstract="true" name="PlantFacilitiesAndInfrastructureMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element id="gevo_Series2020AWarrantsMember" abstract="true" name="Series2020AWarrantsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType" />
  <xsd:element name="RevenueAndCostOfGoodsSoldAbstract" id="gevo_RevenueAndCostOfGoodsSoldAbstract" type="xbrli:stringItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NorthwestIowaMember" id="gevo_NorthwestIowaMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCostsShares" id="gevo_IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCostsShares" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCosts" id="gevo_IssuanceOfCommonStockAndCommonStockWarrantsNetOfIssueCosts" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="ProceedsFromIssuanceOfCommonStockAndCommonStockWarrants" id="gevo_ProceedsFromIssuanceOfCommonStockAndCommonStockWarrants" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="NoncashInterestCapitalizedToConstructionInProgress" id="gevo_NoncashInterestCapitalizedToConstructionInProgress" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="OtherHydrocarbonRevenueEthanolIsooctaneIbaMember" id="gevo_OtherHydrocarbonRevenueEthanolIsooctaneIbaMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LicensingAndDevelopmentRevenueMember" id="gevo_LicensingAndDevelopmentRevenueMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="RenewableNaturalGasFacilitiesOriginalDesignCapacity" id="gevo_RenewableNaturalGasFacilitiesOriginalDesignCapacity" type="dtr-types:energyItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="LiabilityClassifiedRestrictedStockAwardsMember" id="gevo_LiabilityClassifiedRestrictedStockAwardsMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="EngineeringFeePayable" id="gevo_EngineeringFeePayable" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="WarrantsExercised" id="gevo_WarrantsExercised" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
</xsd:schema>
